全文获取类型
收费全文 | 3700篇 |
免费 | 255篇 |
国内免费 | 347篇 |
专业分类
化学 | 970篇 |
晶体学 | 16篇 |
力学 | 1412篇 |
综合类 | 39篇 |
数学 | 786篇 |
物理学 | 1079篇 |
出版年
2024年 | 3篇 |
2023年 | 63篇 |
2022年 | 39篇 |
2021年 | 55篇 |
2020年 | 84篇 |
2019年 | 84篇 |
2018年 | 100篇 |
2017年 | 107篇 |
2016年 | 117篇 |
2015年 | 115篇 |
2014年 | 176篇 |
2013年 | 319篇 |
2012年 | 133篇 |
2011年 | 197篇 |
2010年 | 160篇 |
2009年 | 220篇 |
2008年 | 208篇 |
2007年 | 221篇 |
2006年 | 216篇 |
2005年 | 182篇 |
2004年 | 205篇 |
2003年 | 139篇 |
2002年 | 136篇 |
2001年 | 107篇 |
2000年 | 109篇 |
1999年 | 125篇 |
1998年 | 138篇 |
1997年 | 103篇 |
1996年 | 61篇 |
1995年 | 67篇 |
1994年 | 50篇 |
1993年 | 43篇 |
1992年 | 50篇 |
1991年 | 47篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 10篇 |
1985年 | 14篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1971年 | 2篇 |
1969年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有4302条查询结果,搜索用时 375 毫秒
71.
A. V. Tvardovskii A. A. Fomkin Yu. I. Tarasevich A. I. Zhukova 《Russian Chemical Bulletin》1995,44(8):1419-1421
The hysteresis of sorptive deformation of sorbents has been studied for the first time. Based on the results obtained, it is assumed that the deformation of sorbents could be the universal reason for the sorptive hysteresis.For Part 1, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1477–1479, August, 1995. 相似文献
72.
From the measurements of surface potentials of quartz capillaries before and after adsorption of poly(ethylene oxides) (PEO) of various molecular mass, an assessment of the equilibrium hydrodynamic thickness of the adsorption layers has been obtained. The results have been compared with those of independent measurements of . The flow of the polymer solution under increasing pressure drops at the ends of a capillary, which causes the corresponding shear stress () on the surface of adsorbed PEO layers, results in the deformation of the latter, which manifests itself in decreasing 5. The values decrease by several times when the shear stress rises to 2×102 N m–2. Such values of have been obtained using thin capillaries (r = 5÷6 mm) and by application of the capillary electrokinetic method with pressure drops up to 5÷6 MPa.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 31–37, January, 1994. 相似文献
73.
A study on the ductile deformation domain of the brittle fault in the shallow level ofthe crust is a new probe field for the modern structural geology. Taking the southern Jiang-su Province area as an example the orientation measurement of quartz crystals, the com-positional texture observation of three pressure sensitive minerals and the rheological param-eter determination of dislocation densities, etc. have been demonstrated and analysed basedon typical samples in the present paper. In addition, their generation mechanisms arealso discussed from the cataclastic rheology, the dynamic differentiation and the simpleshearing, specially, from the Ode strength theory. Finally, a generative relationship betweenthe ductile deformation domain of the brittle fault system, in the regional layer--slip andthe formation of the stratabound ore deposit is shown as well. 相似文献
74.
均相催化剂产生于50年代末期,但由于活性很低而末引起重视。80年代初,由于发现MAO具有良好的助催化能力而使均相催化剂得到了很大发展,涌现了多种催化体系,广泛地使α-烯烃及其衍生物立体选择性聚合,开辟了配位聚合研究的新领域,本文对均相催化剂的产生,发展及现状作了综述评述。 相似文献
75.
76.
Xin Wang 《Journal of organometallic chemistry》2005,690(12):2934-2940
Preparation of two imidazolium salts, two monomeric nickel(II) and one cobalt(II) complexes bearing imidazolium ligands is described, The solid-state structures of these compounds have determined by single-crystal X-ray diffraction. After activation with methylaluminoxane (MAO) the nickel complexes show moderate catalytic activities of up to 6 × 105 g PE mol−1Ni h−1 for polymerization of ethylene. Catalytic activities, molecular weights have been investigated under the various reaction conditions. 相似文献
77.
Michael R. Buchmeiser 《Monatshefte für Chemie / Chemical Monthly》2003,134(3):327-342
Summary. The metathesis polymerization, respectively cyclopolymerization, of 1-alkynes and 1,6-heptadiynes using well-defined group
VIA transition metal initiators is summarized. For purposes of comparison, selected quaternary catalytic systems used as alternatives
as well as the properties of the resulting materials will be presented. Special consideration is given to the mechanistic
advancements that have been made during the last decade, which allow the tailor-made synthesis of conjugated materials with
interesting optical and electronic properties.
E-mail: michael.r.buchmeiser@uibk.ac.at
Received November 20, 2002; accepted November 21, 2002 相似文献
78.
Valente Gómez-Benítez 《Tetrahedron letters》2006,47(29):5059-5062
[NiCl{C6H3-2,6-(OPPh2)2}] efficiently catalyzes the thiolation of iodobenzene with a broad scope of disulfides in the presence of zinc, the coupled products are obtained in excellent and in many cases nearly quantitative yields. 相似文献
79.
采用均相反应的方法合成了6个含羟基芳基或氨基芳基的磷酰胺酯衍生物:[(ClCH_2CH_2)_2NP(O)(OPh)(XArY)](X:O,NH;Y:m或p-OH或NH_2).用元素分析、红外光谱、氢核磁共振谱及质谱证实了它们的组成及结构. 相似文献
80.
György Schultz Tamás Nagy Gustavo Portalone Fabio Ramondo István Hargittai Aldo Domenicano 《Structural chemistry》1993,4(3):183-190
The molecular structure and benzene ring distortions of ethynylbenzene have been investigated by gas-phase electron diffraction and ab initio MO calculations at the HF/6-31G* and 6-3G** levels. Least-squares refinement of a model withC
2v, symmetry, with constraints from the MO calculations, yielded the following important bond distances and angles:r
g(C
i
-C
o
)=1.407±0.003 Å,r
g(C
o
-C
m
)=1.397±0.003 Å,r
g(C
m
-C
p
)=1.400±0.003 Å,r
g(Cr
i
-CCH)=1.436 ±0.004 Å,r
g(C=C)=1.205±0.005 Å, C
o
-C
i
-C
o
=119.8±0.4°. The deformation of the benzene ring of ethynylbenzene given by the MO calculations, including o-Ci-Co=119.4°, is insensitive to the basis set used and agrees with that obtained by low-temperature X-ray crystallography for the phenylethynyl fragment, C6H5-CC-, in two different crystal environments. The partial substitution structure of ethynylbenzene from microwave spectroscopy is shown to be inaccurate in the ipso region of the benzene ring. 相似文献